女主人公马莉（周莉饰）外号“黑蝴蝶”，本是一个名活动江湖的江洋大盗。经过几年的监狱改造，马莉决定金盆洗手。马莉过去的马仔刘光明如今已成为偷盗团伙的老大，他想把出狱的马莉到麾下，干一票惊天大案；偷窃拍卖公司价值数千万的古画，但马莉坚决回绝了刘光明，刘光明施尽手段，把马莉逼向了生活的绝境。 男主人公...郑武（吴若甫饰）是马莉的初恋情人，如今是一家贸易公司的老总。马莉与郑武再度邂逅，得知马莉的处境，郑武慷慨相助，给马莉出谋划策，郑武让马莉假意与刘光明合作，等拿到古画之后，再与警方联手，一举铲除刘光明团伙。马莉对郑武言听计从，开始和刘光明的合作，马莉万万没有想到的，她被郑武的虚伪表象蒙蔽了。所有的一切，都是郑武和刘光明事先设计好的陷阱，而刘光明也只是郑武的一颗棋子而已，在盗窃古画的背后，还有一个更大的阴谋阴谋，阴谋的主使者正是表面文质彬彬的郑武。 不知不觉中，一张危险而又恐怖的大网已经笼罩在马莉周围……
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